Surgery of fullerenes

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Surgery of fullerenes.

Recent attempts at the synthesis of endohedral fullerenes by organic reactions, so-called "molecular surgery" methods, are surveyed. The creation of an opening on the surface of fullerene cages allowed insertion of He, H(2), H(2)O, or CO within the cages. An effective route to "suture" an opening was established to realize a new endohedral fullerene, H(2)@C(60). Further development of this oper...

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Antigenicity of fullerenes: antibodies specific for fullerenes and their characteristics.

The recent interest in using Buckminsterfullerene (fullerene) derivatives in biological systems raises the possibility of their assay by immunological procedures. This, in turn, leads to the question of the ability of these unprecedented polygonal structures, made up solely of carbon atoms, to induce the production of specific antibodies. Immunization of mice with a C60 fullerene derivative con...

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Medicinal applications of fullerenes

Fullerenes have attracted considerable attention in different fields of science since their discovery in 1985. Investigations of physical, chemical and biological properties of fullerenes have yielded promising information. It is inferred that size, hydrophobicity, three-dimensionality and electronic configurations make them an appealing subject in medicinal chemistry. Their unique carbon cage ...

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New Expansion for Certain Isomers of Various Classes of Fullerenes

This paper is dedicated to propose an algorithm in order to generate the certain isomers of some well-known fullerene bases. Furthermore, we enlist the bipartite edge frustration correlated with some of symmetrically distinct innite families of fullerenes generated by the oered process.

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Bipartizing fullerenes

A fullerene graph is a cubic bridgeless planar graph with twelve 5-faces such that all other faces are 6-faces. We show that any fullerene graph on n vertices can be bipartized by removing O( √ n) edges. This bound is asymptotically optimal.

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ژورنال

عنوان ژورنال: Chemical Communications

سال: 2008

ISSN: 1359-7345,1364-548X

DOI: 10.1039/b811738a